Diffusion Large Language Models (dLLMs) refine tokens iteratively but commit them irreversibly, leading to a "stability lag" where early decisions remain fragile even after being written. We reveal that Post-Training Quantization (PTQ) error easily flips these borderline decisions at the write frontier, which are then permanently locked in and amplified. To address this, we propose Frontier-Aware Instability-Reweighted Calibration (FAIR-Calib), a two-stage PTQ framework for dLLMs. Stage I probes a full-precision teacher to estimate a position prior that combines frontier hits and masked-stage reliability. Stage II performs off-policy, layer-wise calibration by minimizing a reweighted hidden-state MSE, effectively prioritizing the protection of fragile frontier states without requiring expensive end-to-end diffusion rollouts. We further theoretically justify our weighted objective as a surrogate for output KL divergence. Empirically, FAIR-Calib consistently outperforms state-of-the-art baselines on LLaDA and Dream (W4A4), significantly reducing frontier decision flips and suppressing post-commit mismatches across diverse benchmarks.
Diffusion large language models (DLLMs) have recently emerged as a promising alternative to autoregressive LLMs by generating text through iterative masked denoising with bidirectional context. However, their large model sizes and iterative denoising process introduce substantial memory and computational overhead, motivating post-training quantization for efficient deployment. In this paper, we identify two key challenges for low-bit DLLM quantization: state-dependent activation disparity and temporal error accumulation. Masked and unmasked tokens exhibit different activation distributions within each denoising step, while quantization errors can accumulate across steps during iterative decoding. To address these challenges, we propose STaR-Quant, a state-time consistent PTQ framework for DLLMs. STaR-Quant introduces State-Guided Activation Transformation (SGAT) to assign masked and unmasked tokens to different activation transformation spaces with a unified static weight-side transformation. It further introduces Temporal Attention Compensation (TAC) to correct the quantized attention representation via a lightweight block-diagonal affine mapping. Experiments on representative DLLMs demonstrate that STaR-Quant consistently improves low-bit weight-activation quantization over strong PTQ baselines, while delivering up to 1.69x speedup and 3.14x memory saving over FP16 deployment.