Pretrained vision-language models such as CLIP excel at zero-shot recognition but often fail at compositionality, particularly attribute-object and relational structures. Recent studies mitigate this issue by augmenting training with synthetic hard negatives generated by a cascade of large language models and text-to-image models, which incurs substantial pipeline overhead. We instead propose MLLMCLIP, a heterogeneous distillation framework that transfers multimodal knowledge directly from a generative Multimodal Large Language Model (MLLM) teacher into a discriminative CLIP student, bypassing synthetic data entirely. To bridge the architectural mismatch between the two paradigms, we introduce an attention-based per-layer token selection and a CKA-based distillation loss. Compared to prior CLIP-enhancement methods, MLLMCLIP achieves state-of-the-art compositional accuracy while delivering consistent gains on standard zero-shot classification and image-text retrieval, showing that feature-level distillation strengthens both compositional and general vision-language representation capability.
Contrastively trained vision-language models like CLIP, have made remarkable progress in learning joint image-text representations, but still face challenges in compositional understanding. They often exhibit a "bag-of-words" behavior--struggling to capture the object relations, attribute-object bindings, and word order dependencies. This limitation arises not only from the reliance on global, single-vector representations for optimization, but also from the insufficient exploitation and modeling of the rich compositional information inherently present in paired image text data. In this work, we propose MACCO (MAsked Compositional Concept MOdeling), a framework that masks compositional concepts in one modality and reconstructs them conditioned on the full contextual information from the other, enabling the model to capture and align cross-modal compositional structures more effectively. To facilitate this process, we introduce two auxiliary objectives that jointly align and regularize masked features both inter-modally and intra-modally. Extensive experiments on five compositional benchmarks, along with in-depth analyses, demonstrate that our approach not only significantly enhances compositionality in VLMs but also improves their ability to capture syntactic structure and linguistic information. Additionally, the improved compositionality also benefits text-to-image generation and multimodal large language model. Code is available at https://github.com/hiker-lw/MACCO.