Large language models (LLMs) are increasingly used as AI tutors, but a correct answer is not always a pedagogically appropriate one. In classroom learning, effective help depends not only on correctness, but also on whether a response matches the learner's current foundation, the course sequence, and the timing of concept introduction. Existing evaluations focus mainly on answer quality, leaving this instructional fit under-measured. We present the Pedagogical Suitability Index (PSI), a composite metric of six theory-informed sub-scores that evaluates how well LLM-generated tutoring responses align with learner readiness and curricular progression, and we further use PSI as a structured feedback signal for response improvement. We evaluate four LLM tutors (ChatGPT, Gemini, Gemma4, and Qwen3) across 240 scenario-based evaluations using paired standard and defective prompts, then apply a PSI-guided regeneration protocol to 62 weak-performing cases. Baseline differences across the four tested models were modest overall (PSI range: 0.557 to 0.638), and open-weight and closed models did not exhibit a clear separation in pedagogical fit. Under the tested prompt perturbations, overall PSI remained largely stable (Delta = -0.002), though sub-score trade-offs emerged. More importantly, PSI-guided feedback substantially improved weak-performing cases: 51 of 62 cases improved (82.3%). Focused manual evaluation of the 62 PSI-selected weak cases provides initial evidence that the identified weaknesses are instructionally meaningful and that many PSI-guided regenerations correspond to human-judged improvement. These results suggest that learner- and curriculum-aware alignment may matter more for effective tutoring than model category alone, and that such alignment is both measurable and improvable.
Schema-constrained information extraction from diverse educational and labor-market corpora remains an open challenge in natural language processing because existing pipelines rely primarily on lexical-surface methods that cannot recover implicit competencies, lack grounding in shared taxonomies, and provide no formal measures of extraction reliability or document-level completeness. To address these limitations, this paper proposes a four-stage NLP framework that combines (i) schema-constrained prompting of a two-model frontier-LLM ensemble against a JSON Schema-enforced seven-slot competency formalism, (ii) Sentence-BERT (SBERT) alignment of the extracted records against an eleven-domain ESCO v1.2.1 controlled vocabulary, (iii) a two-tier adjudication protocol that resolves inter-model disagreements, and (iv) a verification mechanism that combines per-slot Cohen's kappa, schema conformance, and document-level completeness audits. The framework is instantiated for a critical application in higher-education quality assurance, namely curriculum-labor market alignment for the ABET-accredited BSc Computer Science program at the United Arab Emirates University. The pipeline extracts 400 competency records from the 85-course 2025-2026 study plan and aligns them, under a five-scope analysis ranging from the computing core to a probability-weighted student trajectory, with 30 job postings (483 requirement clauses) at an SBERT cosine threshold of 0.50. The extractor achieves Cohen's kappa of 0.79 on the skill slot, with 100% schema conformance and 100% document-level completeness. The alignment surfaces interpretable supply-demand gaps of 25.0% in general and transversal skills, 13.8% in algorithms and computational theory, and 12.2% in software engineering and project management, with a near-zero 1.8% gap in artificial intelligence and data science despite 38.6% supply coverage.