Synthetic textbook data has improved language model pre-training, but prior work largely treats the benefit as a property of generated content or local rewriting style. We study a different factor: whether related content is organized into coherent book-level documents. We contribute both a scalable synthesis pipeline and controlled evidence that this organization matters. The pipeline retrieves source material from a pre-training corpus, clusters it into topical units, plans hierarchical tables of contents, and assembles source-grounded sections into complete books (our Full setting), yielding 686K textbooks (32B tokens) across 15,000+ disciplines. Replacing natural books in a mid-training mix with this corpus improves downstream performance by +1.09 on average. Controlled comparisons then disentangle the relevant design factors. A content-matched Split condition holds generated text and tokens fixed but treats each section as an independent document; Full's +1.02 mean gain isolates document packaging. A length-matched RandomConcat control that joins sections from different books remains below Full, ruling out document length alone. A retrieval-pool-matched Rephrase condition independently rewrites individual retrieved documents under the same audience-by-style scheme, without clustering, TOC planning, or book assembly; Full's +1.17 gain demonstrates the value of structured synthesis. On Llama3-8B, Full likewise outperforms both RandomConcat and Natural Books, supporting book-level organization as a useful axis for synthetic pre-training data design.
Post-training of large language models is expensive, and existing efficiency improvements mainly focus on selecting informative samples or designing training schedules. However, data organization itself is usually treated as a static preprocessing step: embedding-based grouping methods construct fixed partitions before training and cannot adapt to the evolving sample exposure during optimization. As a result, all samples receive similar exposure despite their different optimization needs, leading to redundant updates for some samples while leaving others under-optimized. To address this problem, we propose SDO (Structure-Aware Data Organization), a plug-and-play data organization framework with an exposure-driven feedback mechanism that organizes mini-batch composition and sample exposure according to representation-space structure. SDO operates epoch by epoch on frozen external embeddings, avoiding model warm-up training overhead: within each epoch, locality-aware batching forms coherent mini-batches via KNN neighborhood traversal; across epochs, exposure-balanced scheduling records per-sample participation and reduces the sampling probability of over-exposed samples to preserve long-term coverage. Across SFT, DPO, and GRPO, SDO accelerates convergence, with the largest gains observed in the early-to-mid phase, producing more coherent gradients and more balanced accuracy across question types without permanently excluding training samples.